NickelMaghrebV1, Main, Exploration, bibRecord, 000B49

Laser-Induced Fluorescence and Fourier Transform Spectroscopy of NiCl: Identification of a Low-Lying 2Σ+ State (1768 cm−1)

Identifieur interne : 000B49 ( Main/Exploration ); précédent : 000B48; suivant : 000B50

Laser-Induced Fluorescence and Fourier Transform Spectroscopy of NiCl: Identification of a Low-Lying 2Σ+ State (1768 cm−1)

Auteurs : A. Poclet [France] ; Y. Krouti [France] ; T. Hirao ; B. Pinchemel [France] ; P. F. Bernath

Source :

Journal of Molecular Spectroscopy [ 0022-2852 ] ; 2000.

RBID : ISTEX:32C75EEDE6FED3536EF5A23D199824B1EE31CA31

Abstract

From a comparison with the spectrum of NiF, a low-lying 2Σ+ state is expected to lie in the first 2000 cm−1 above the ground X2Π3/2 state of NiCl. The identification of this 2Σ+ (v = 0) state (at 1768 cm−1) has been carried out through the analysis of two electronic transitions 2Π3/2–2Σ+ (22 720 cm−1) and 2Π1/2–2Σ+ (23 210 cm−1) recorded by high-resolution Fourier transform spectroscopy. Dispersed fluorescence spectroscopy allowed these transitions to be located on an absolute energy-level diagram that includes the previously studied electronic states.

Url:

https://api.istex.fr/document/32C75EEDE6FED3536EF5A23D199824B1EE31CA31/fulltext/pdf

DOI: 10.1006/jmsp.2000.8186

Affiliations:

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Le document en format XML

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Laser-Induced Fluorescence and Fourier Transform Spectroscopy of NiCl: Identification of a Low-Lying 2Σ+ State (1768 cm−1)

Laser-Induced Fluorescence and Fourier Transform Spectroscopy of NiCl: Identification of a Low-Lying 2Σ+ State (1768 cm−1)

Source :

Abstract

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